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Lacunary POMs as platforms for the elaboration of functional devices and materials
Functionalization and post-functionalization a step towards polyoxometalate-based materials. A. Proust, B. Matt, R. Villanneau, G. Guillemot, P. Gouzerh, G. Izzet, Chem. Soc. Rev., 41, 7605–7622. Themed issue on Polyoxometalates.
Polyoxometalates (POMs) have remarkable properties and a great deal of potential to meet contemporary societal demands regarding health, environment, energy and information technologies. However, implementation of POMs in various functional architectures, devices (...)
Lacunary POMs as ligands
Connecting ruthenium substituted Keggin-type tungstophosphates by oxotungstic bridges : Evidence for the steric effect of RuL32+ (L3 = η6-arene, (DMSO)3) fragments.
D. Laurencin, R. Thouvenot, K. Boubekeur, P. Gouzerh, A. Proust, C. R. Chimie 2012, 15, 135-142 (Thematic issue Polyoxometalates, metal wires and other “polymetallic” complexes : structure, properties, theoretical modelling – A tribute to M.-M. Rohmer).
The intrinsic reactivity of the organoruthenium-grafted tungstophosphates (...)
Keplerate chemistry (in collaboration with A. Müller, Bielefeld – Germany)
From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry
A. Müller, P. Gouzerh, Chem. Soc. Rev., 2012, 41, 7431-7463.
The porous sphere- and ring-shaped polyoxometalate-type nano-objects with unique properties offer the option for the investigation of a variety of phenomena of interdisciplinary interest including those under confined conditions, for instance related to fundamental aspects of the hydrophobic (...)
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