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Accueil > Les équipes > Réactivité organométallique et catalyse pour la synthèse (ROCS) > Publications

Publications

publié le , mis à jour le

2017

2016

« C-2 Alkylation and Alkenylation of Indoles Catalyzed by a Low-Valent Cobalt Complex in the Absence of Reductant ». [Online]. Available: http://pubs.acs.org/doi/pdf/10.1021/acs.orglett.6b00939.
D. Diamante, S. Gabrieli, T. Benincori, G. Broggini, J. Oble, et G. Poli, « Dehydrogenative Allylic Aminations of But-3-enoic Acid Derivatives », ResearchGate.
F. J. S. Duarte, G. Poli, et M. J. Calhorda, « Mechanistic Study of the Direct Intramolecular Allylic Amination Reaction Catalyzed by Palladium(II) », ACS Catalysis, vol. 6, nᵒ 3, p. 1772-1784.
B. J. Fallon, V. Corcé, M. Amatore, C. Aubert, F. Chemla, F. Ferreira, A. Perez-Luna, et M. Petit, « A well-defined low-valent cobalt catalyst Co(PMe3)4 with dimethylzinc: a simple catalytic approach for the reductive dimerization of benzyl halides ».
C. Fopp, K. Isaac, E. Romain, F. Chemla, F. Ferreira, O. Jackowski, M. Oestreich, et A. Perez-Luna, « Stereodivergent Synthesis of β-Heteroatom-Substituted Vinyl­silanes by Sequential Silylzincation–Copper(I)-Mediated Electrophilic­ Substitution », Synthesis.
J. R. Hernandez, F. Chemla, F. Ferreira, O. Jackowski, J. Oble, A. Perez-Luna, et G. Poli, « tert-Butanesulfinamides as Nitrogen Nucleophiles in Carbon–Nitrogen Bond Forming Reactions », CHIMIA International Journal for Chemistry, vol. 70, nᵒ 1, p. 84-92.
D. Lebœuf, L. Marin, B. Michelet, A. Perez-Luna, R. Guillot, E. Schulz, et V. Gandon, « Harnessing the Lewis Acidity of HFIP through its Cooperation with a Calcium(II) Salt: Application to the Aza-Piancatelli Reaction », Chemistry (Weinheim an Der Bergstrasse, Germany), vol. 22, nᵒ 45, p. 16165-16171.
M. M. Lorion, F. J. S. Duarte, M. J. Calhorda, J. Oble, et G. Poli, « Opening the Way to Catalytic Aminopalladation/Proxicyclic Dehydropalladation: Access to Methylidene γ-Lactams », Organic Letters, vol. 18, nᵒ 5, p. 1020-1023.
M. M. Lorion, J. Oble, et G. Poli, « Palladium catalyzed oxidative aminations and oxylations: where are we? », Pure and Applied Chemistry, vol. 88, nᵒ 4, p. 381–389.
R. Maazaoui, M. Pin-Nó, K. Gervais, R. Abderrahim, F. Ferreira, A. Perez-Luna, F. Chemla, et O. Jackowski, « Domino Methylenation/Hydrogenation of Aldehydes and Ketones by Combining Matsubara's Reagent and Wilkinson's Catalyst », European Journal of Organic Chemistry, p. n/a-n/a.
V. N. Bochatay, « (6) 4-Amino-1-allenylsilanes from 4-Amino Propargylic Acetates through a Silylzincation / Elimination Sequence ». [Online]. Available: https://www.thieme-connect.com/products/ejournals/pdf/10.1055/s-0035-1562429.pdf?update=true.
F. Roudesly, J. Oble, et G. Poli, « Metal-catalyzed CH activation/functionalization: The fundamentals », Journal of Molecular Catalysis A: Chemical.
V. Scalcon, S. Top, H. Z. S. Lee, A. Citta, A. Folda, A. Bindoli, W. K. Leong, M. Salmain, A. Vessières, G. Jaouen, et M. P. Rigobello, « Osmocenyl-tamoxifen derivatives target the thioredoxin system leading to a redox imbalance in Jurkat cells », Journal of Inorganic Biochemistry, vol. 160, p. 296-304.
J. T. Vázquez, A. Perez-Luna, D. M. Aparicio, I. Zelocualtecatl Montiel, F. García Alvarez, J. R. Juárez, L. Orea, D. Gnecco, A. Mendoza, F. Chemla, F. Ferreira, et O. Jackowski, « Asymmetric Tandem Conjugate Addition-Aldol Condensation with N-Acryloyloxazolidines derived from 2-Phenylglycinol », Asian Journal of Organic Chemistry, p. n/a-n/a.

2015

B. J. Fallon, E. Derat, M. Amatore, C. Aubert, F. Chemla, F. Ferreira, A. Perez-Luna, et M. Petit, « C–H Activation/Functionalization Catalyzed by Simple, Well-Defined Low-Valent Cobalt Complexes », Journal of the American Chemical Society, vol. 137, nᵒ 7, p. 2448-2451.
F. Louafi, M. M. Lorion, J. Oble, et G. Poli, « Dichotomous Reaction Pathways for the Oxidative Palladium(II)-Catalyzed Intramolecular Acyloxylation of Alkenes », Synlett, vol. 26, nᵒ 16, p. 2237-2242.

2014

I. Erray, J. Oble, G. Poli, et F. Rezgui, « Regioselective <i>S</i> -allylation of thiols with cyclic Baylis–Hillman acetates », Journal of Sulfur Chemistry, vol. 35, nᵒ 2, p. 128-136.
I. Erray, F. Rezgui, J. Oble, et G. Poli, « Microwave-Assisted Palladium-Catalyzed Allylation of beta-Enaminones », Synlett, vol. 25, nᵒ 15, p. 2196-2200.
C. Kammerer, G. Prestat, D. Madec, et G. Poli, « Synthesis of γ-Lactams and γ-Lactones via Intramolecular Pd-Catalyzed Allylic Alkylations », Accounts of Chemical Research, vol. 47, nᵒ 12, p. 3439-3447.
F. Liron, J. Oble, M. M. Lorion, et G. Poli, « Direct Allylic Functionalization Through Pd-Catalyzed C-H Activation: Direct Allylic Functionalization by Pd-Catalyzed C-H Activation », European Journal of Organic Chemistry, vol. 2014, nᵒ 27, p. 5863-5883.
M. M. Lorion, F. Nahra, V. L. Ly, C. Mealli, A. Messaoudi, F. Liron, J. Oble, et G. Poli, « Digging into the mechanism of oxidative Pd(II)-catalyzed aminations », Chimica Oggi-Chemistry Today, vol. 32, nᵒ 5, p. 30-34.
L. Mistico, E. Ay, V. Huynh, A. Bourderioux, F. Chemla, F. Ferreira, J. Oble, A. Perez-Luna, G. Poli, et G. Prestat, « Reactivity of tert-butanesulfinamides in palladium-catalyzed allylic substitutions », Journal of Organometallic Chemistry, vol. 760, p. 124-129.
J. Rajabi, M. M. Lorion, V. L. Ly, F. Liron, J. Oble, G. Prestat, et G. Poli, « Dormant versus Evolving Aminopalladated Intermediates: Toward a Unified Mechanistic Scenario in Pd <sup>II</sup> -Catalyzed Aminations », Chemistry - A European Journal, vol. 20, nᵒ 6, p. 1539-1546.
B. Riflade, D. Lachkar, J. Oble, J. Li, S. Thorimbert, B. Hasenknopf, et E. Lacote, « Pd-Containing Organopolyoxometalates Derived from Dawson Polyoxometalate [P2W15V3O62](9-): Lewis Acidity and Dual Site Catalysis », Organic Letters, vol. 16, nᵒ 15, p. 3860-3863.
M. Rigamonti, G. Prestat, G. Broggini, et G. Poli, « Synthesis of 1,4-benzodiazepinones via palladium-catalysed allene carbopalladation/amination domino sequence », Journal of Organometallic Chemistry, vol. 760, p. 149-155.
E. Romain, C. Fopp, F. Chemla, F. Ferreira, O. Jackowski, M. Oestreich, et A. Perez-Luna, « Trans-Selective Radical Silylzincation of Ynamides », Angewandte Chemie-International Edition, vol. 53, nᵒ 42, p. 11333-11337.

2013

C. Caumes, N. Delsuc, R. B. Azza, I. Correia, F. Chemla, F. Ferreira, L. Carlier, A. P. Luna, R. Moumné, O. Lequin, et P. Karoyan, « Homooligomers of substituted prolines and β-prolines: syntheses and secondary structure investigation », New Journal of Chemistry, vol. 37, nᵒ 5, p. 1312-1319.
F. Chemla, F. Dulong, F. Ferreira, et A. Perez-Luna, « Radical zinc-atom-transfer-based carbozincation of haloalkynes with dialkylzincs », Beilstein Journal of Organic Chemistry, vol. 9, p. 236-245.
A. Denichoux, M. Cyklinsky, F. Chemla, F. Ferreira, et A. Pérez-Luna, « Conjugated Enyne Synthesis by Rearrangement of Acetylenic Epoxides Mediated by Low-Valence Organotitanium and Organozirconium Reagents », Synlett, vol. 24, nᵒ 08, p. 1001-1005.
A. Denichoux, L. Debien, M. Cyldinsky, M. Kaci, F. Chemla, F. Ferreira, et A. Perez-Luna, « Three-Carbon Homologation of Diorganozincs with Lithiated Acetylenic Epoxides », Journal of Organic Chemistry, vol. 78, nᵒ 1, p. 134-145.
M. M. Lorion, D. Gasperini, J. Oble, et G. Poli, « Palladium-Catalyzed Arylic/Allylic Aminations: Permutable Domino Sequences for the Synthesis of Dihydroquinolines from Morita-Baylis-Hillman Adducts », Organic Letters, vol. 15, nᵒ 12, p. 3050-3053.
M. M. Lorion, B. Matt, S. Alves, A. Proust, G. Poli, J. Oble, et G. Izzet, « Versatile Post-functionalization of Polyoxometalate Platforms By Using An Unprecedented Range of Palladium-Catalyzed Coupling Reactions », Chemistry-a European Journal, vol. 19, nᵒ 38, p. 12607-12612.
B. Riflade, J. Oble, L. Chenneberg, E. Derat, B. Hasenknopf, E. Lacôte, et S. Thorimbert, « Hybrid polyoxometalate palladacycles: DFT study and application to the Heck reaction », Tetrahedron, vol. 69, nᵒ 27–28, p. 5772-5779.

2012

J. Bejjani, C. Botuha, F. Chemla, F. Ferreira, S. Magnus, et A. Pérez-Luna, « Metallotropic Equilibrium and Configurational Stability of 3-Chloro-1-(trimethylsilyl)propargyl and -allenyl Metals: Comparative Study among Lithium, Titanium, and Zinc », Organometallics, vol. 31, nᵒ 13, p. 4876-4885.
A. Boutier, C. Kammerer-Pentier, N. Krause, G. Prestat, et G. Poli, « Pd-Catalyzed Asymmetric Synthesis of N-Allenyl Amides and Their Au-Catalyzed Cycloisomerizative Hydroalkylation: A New Route Toward Enantioenriched Pyrrolidones », Chemistry – A European Journal, vol. 18, nᵒ 13, p. 3840–3844.
G. Broggini, E. Borsini, A. Fasana, G. Poli, et F. Liron, « Transition-Metal-Catalyzed Hydroamination and Carboamination Reactions of Anthranilic Allenamides as a Route to 2-Vinyl- and 2-(α-Styryl)quinazolin-4-one Derivatives », European Journal of Organic Chemistry, vol. 2012, nᵒ 19, p. 3617–3624.
S. Giboulot, F. Liron, G. Prestat, B. Wahl, M. Sauthier, Y. Castanet, A. Mortreux, et G. Poli, « Pd-catalyzed domino carbonylative–decarboxylative allylation: an easy and selective monoallylation of ketones », Chemical Communications, vol. 48, nᵒ 47, p. 5889-5891.
C. Kammerer-Pentier, A. Diez Martinez, J. Oble, G. Prestat, P. Merino, et G. Poli, « Dual reactivity of O-α-allenyl esters under palladium(0) catalysis: From carbopalladation/allylic alkylation domino sequence to decarboxylative allenylation », Journal of Organometallic Chemistry, vol. 714, p. 53-59.
S. Ouizem, F. Chemla, F. Ferreira, et A. Perez-Luna, « Synthesis of Enantiopure 5-Substituted 2,3-Methanopyrrolidines by Cyclization of Enantiopure alpha-Branched alpha-N-Homoallylamino Nitriles », Synlett, nᵒ 9, p. 1374-1378.
B. Wahl, H. Bonin, A. Mortreux, S. Giboulot, F. Liron, G. Poli, et M. Sauthier, « A General and Efficient Method for the Alkoxycarbonylation of alpha-Chloro Ketones », Advanced Synthesis & Catalysis, vol. 354, nᵒ 16, p. 3105-3114.
B. Wahl, S. Giboulot, A. Mortreux, Y. Castanet, M. Sauthier, F. Liron, et G. Poli, « Straightforward Synthesis of Allylated Keto Esters: The Palladium-Catalysed Haloketone Alkoxycarbonylation/ Allylation Domino Reaction », Advanced Synthesis & Catalysis, vol. 354, nᵒ 6, p. 1077–1083.

2011

X. Bantreil, G. Prestat, A. Moreno, D. Madec, P. Fristrup, P. - O. Norrby, P. S. Pregosin, et G. Poli, « γ- and δ-Lactams through Palladium-Catalyzed Intramolecular Allylic Alkylation: Enantioselective Synthesis, NMR Investigation, and DFT Rationalization », Chemistry – A European Journal, vol. 17, nᵒ 10, p. 2885–2896.
S. Cacchi, G. Fabrizi, A. Goggiamani, A. Iazzetti, D. Madec, G. Poli, et G. Prestat, « Functionalized 2,3-dihydrofurans via palladium-catalyzed oxyarylation of alpha-allyl-beta-ketoesters », Organic & Biomolecular Chemistry, vol. 9, nᵒ 24, p. 8233-8236.
M. Cyklinsky, C. Botuha, F. Chemla, F. Ferreira, et A. Perez-Luna, « Diastereoselective Synthesis of Enantiopure Homopropargylic N-tert-Butylsulfinylamines », Synlett, nᵒ 18, p. 2681-2684.
J. Kleimark, G. Prestat, G. Poli, et P. - O. Norrby, « Palladium-Catalyzed Allylic Sulfinylation and the Mislow–Braverman–Evans Rearrangement », Chemistry – A European Journal, vol. 17, nᵒ 50, p. 13963–13965.
G. Le Duc, E. Bernoud, G. Prestat, S. Cacchi, G. Fabrizi, A. Iazzetti, D. Madec, et G. Poli, « Palladium-Catalyzed Aromatic Sulfonylation: A New Catalytic Domino Process Exploiting in situ Generated Sulfinate Anions », Synlett, nᵒ 20, p. 2943-2946.
J. Louvel, F. Chemla, E. Demont, F. Ferreira, et A. Perez-Luna, « Synthesis of (-)-Swainsonine and (-)-8-epi-Swainsonine by the Addition of Allenylmetals to Chiral alpha,beta-Alkoxy Sulfinylimines », Organic Letters, vol. 13, nᵒ 24, p. 6452-6455.
J. Louvel, F. Chemla, E. Demont, F. Ferreira, A. Perez-Luna, et A. Voituriez, « Stereoselective Synthesis of syn-beta-Amino Propargylic Ethers: Application to the Asymmetric Syntheses of (+)-beta-Conhydrine and (-)-Balanol », Advanced Synthesis & Catalysis, vol. 353, nᵒ 11-12, p. 2137-2151.
E. Zaborova, J. Deschamp, S. Guieu, Y. Blériot, G. Poli, M. Ménand, D. Madec, G. Prestat, et M. Sollogoub, « Cavitand supported tetraphosphine: cyclodextrin offers a useful platform for Suzuki-Miyaura cross-coupling », Chemical Communications, vol. 47, nᵒ 32, p. 9206-9208.

2010

E. Bernoud, G. Le Duc, X. Bantreil, G. Prestat, D. Madec, et G. Poli, « Aryl Sulfoxides from Allyl Sulfoxides via [2,3]-Sigmatropic Rearrangement and Domino Pd-Catalyzed Generation/Arylation of Sulfenate Anions », Organic Letters, vol. 12, nᵒ 2, p. 320-323.
C. Botuha, F. Chemla, F. Ferreira, J. Louvel, et A. Perez-Luna, « Allenylzincs and tert-butylsulfinylimines: a fruitful marriage for synthesis », Tetrahedron-Asymmetry, vol. 21, nᵒ 9-10, p. 1147-1153.
F. Dénès, A. Pérez-Luna, et F. Chemla, « Addition of Metal Enolate Derivatives to Unactivated Carbon−Carbon Multiple Bonds », Chemical Reviews, vol. 110, nᵒ 4, p. 2366-2447.
S. Guieu, E. Zaborova, Y. Blériot, G. Poli, A. Jutand, D. Madec, G. Prestat, et M. Sollogoub, « Can Hetero-Polysubstituted Cyclodextrins be Considered as Inherently Chiral Concave Molecules? », Angewandte Chemie International Edition, vol. 49, nᵒ 13, p. 2314–2318.
J. Louvel, C. Botuha, F. Chemla, E. Demont, F. Ferreira, et A. Pérez-Luna, « Asymmetric Total Synthesis of (+)-6-epi-Castanospermine by the Stereoselective Formation of a syn,anti Acetylenic 2-Amino-1,3-diol Stereotriad », European Journal of Organic Chemistry, vol. 2010, nᵒ 15, p. 2921–2926.
G. Maitro, G. Prestat, D. Madec, et G. Poli, « An escapade in the world of sulfenate anions: generation, reactivity and applications in domino processes », Tetrahedron-Asymmetry, vol. 21, nᵒ 9-10, p. 1075-1084.
S. Ouizem, S. Cheramy, C. Botuha, F. Chemla, F. Ferreira, et A. Pérez-Luna, « Cyclization of Zincated α-N-Homoallylamino Nitriles: A New Entry to Enantiopure 2,3-Methanopyrrolidines », Chemistry – A European Journal, vol. 16, nᵒ 42, p. 12668–12677.
S. Vogel, X. Bantreil, G. Maitro, G. Prestat, D. Madec, et G. Poli, « Palladium-catalyzed intramolecular allylic alkylation of α-sulfinyl carbanions: a new asymmetric route to enantiopure γ-lactams », Tetrahedron Letters, vol. 51, nᵒ 11, p. 1459-1461.

2009

X. Bantreil, G. Prestat, D. Madec, P. Fristrup, et G. Poli, « Enantioselective γ-Lactam Synthesis via Palladium-Catalyzed Intramolecular Asymmetric Allylic Alkylation », Synlett, vol. 2009, nᵒ 09, p. 1441-1444.
F. Ferreira, C. Botuha, F. Chemla, et A. Pérez-Luna, « tert-Butanesulfinimines: structure, synthesis and synthetic applications », Chemical Society Reviews, vol. 38, nᵒ 4, p. 1162-1186.
F. Ferreira, C. Botuha, F. Chemla, et A. Pérez-Luna, « Expeditious Synthesis of a Common Intermediate of l-1-Deoxyallonojirimycin and l-1-Deoxymannojirimycin », The Journal of Organic Chemistry, vol. 74, nᵒ 5, p. 2238-2241.
B. Hélal, F. Ferreira, C. Botuha, F. Chemla, et A. Pérez-Luna, « Concise Synthesis of (2S,3R)-3-Hydroxy-2-phenylpiperidine: An Advanced Key Intermediate of Human Non-Peptide NK-1 Receptor Antagonists », Synlett, vol. 2009, nᵒ 19, p. 3115-3118.
C. Kammerer, G. Prestat, D. Madec, et G. Poli, « Phosphine-Free Palladium-Catalyzed Allene Carbopalladation/Allylic Alkylation Domino Sequence: A New Route to 4-(α-Styryl) γ-Lactams », Chemistry – A European Journal, vol. 15, nᵒ 17, p. 4224–4227.
F. Liron, F. Fontana, J. - O. Zirimwabagabo, G. Prestat, J. Rajabi, C. L. Rosa, et G. Poli, « A New Cross-Coupling-Based Synthesis of Carpanone », Organic Letters, vol. 11, nᵒ 19, p. 4378-4381.
F. Nahra, F. Liron, G. Prestat, C. Mealli, A. Messaoudi, et G. Poli, « Striking AcOH Acceleration in Direct Intramolecular Allylic Amination Reactions », Chemistry – A European Journal, vol. 15, nᵒ 42, p. 11078–11082.
C. Séguin, F. Ferreira, C. Botuha, F. Chemla, et A. Pérez-Luna, « High-Yielding Synthesis of Sphingoid-Type Bases », The Journal of Organic Chemistry, vol. 74, nᵒ 18, p. 6986-6992.
A. Voituriez, A. Pérez-Luna, F. Ferreira, C. Botuha, et F. Chemla, « Stereo- and Enantioselective Synthesis of Acetylenic 2-Amino-1,3-diol Stereotriads », Organic Letters, vol. 11, nᵒ 4, p. 931-934.